Cis-3-Hexenyl Isovalerate
Cis-3-Hexenyl Isovalerate
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Creates photorealistic fruit with natural complexity.
Adds mouth-watering realism to any composition.
The ultimate juicy green apple for authentic fruit notes.
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Aroma Chemicals | Green Collection
CAS: 35154-45-1 Classification: Top Note[i]This material captures the exact sensation of biting into a crisp Granny Smith apple—complete with the mouth-watering juice and complex ripeness. The isovalerate portion provides the secret weapon: a subtle funky, cheese-like undertone that mimics the natural fermentation processes in real fruit ripening.
This sophisticated funkiness prevents fruit accords from smelling flat or synthetic. The slight valerian-like character grounds the bright apple notes, creating three-dimensional realism that tricks the nose into perceiving genuine fruit flesh. You can leverage this complexity to transform basic fruity compositions into convincing, textured experiences.
Use this when you need to move beyond generic fruit notes into photorealistic territory. Its exceptional tenacity carries the juicy character from top notes into the heart, whilst its natural occurrence in black tea and herbs opens doors to sophisticated aromatic compositions. The key is understanding that the slight "off" note isn't a flaw—it's the source of its naturalism.
Disclaimer: where applicable, references to third-party perfumes, brand names and trade marks are solely for identification and comparison. This is an independently developed Fraterworks formulation, not the original, and is not affiliated with or endorsed by any brand or trade mark owner.
- IFRA 51
- Details coming soon…
- Odour Family
- Green
- Appearance
- Colourless liquid
- Longevity
- Lasts 4 hours on a smelling strip.
- INCI Name
- CIS-3-HEXENYL ISOVALERATE
- IUPAC Name
- (3Z)-Hex-3-en-1-yl 3-methylbutanoate
Cis-3-hexenyl isovalerate delivers a powerfully juicy green apple character with fresh blueberry and pineapple facets, enhanced by subtle cheese-like and valerian undertones that add remarkable naturalism.
Creates photorealistic apple accords; adds succulent texture to fruit compositions; naturalises synthetic formulas.
General Information
General Information
Like most suppliers and makers of quality raw materials for fragrances, we do not filter many of our products. This ensures that no odiferous matter is lost prior to use but can result in the appearance of small particles or slight clouding.
All alcoholic fragrances should be macerated for up to a month and then chilled in a moderate freezer overnight before being filtered fine. This will remove all cloudiness or detritus and is the industry norm.
IFRA Standards
IFRA Standards
Permitted amounts in finished product:
IFRA 51: Coming Soon
IFRA 49: Coming Soon
These are derived from calculated concentrations which do not replace chromatographic quantification on individual lots. Disclaimer...
For Trade Use Only
For Trade Use Only
Our products are intended as building blocks in the perfume creation process; they are not to be applied to the skin undiluted.
These raw materials are for use by the perfumery trade only.

Usage in Perfumery
Cis-3-Hexenyl Isovalerate appears in 1% of the perfumes we have analysed, at a median of tr. of the concentrate.
- Odour
- Apple, green, fruity, fresh, tropical
- Family
- Green
- Substantivity
- 4 hours on a smelling strip
- Benzyl Acetate, Natural
- Phenyl Ethyl Alcohol
- gamma.-Bisabolene
- Leaf alcohol
- beta.-Farnesene
- Aerolide®
- Patchouli Heart N.3 PA60
- Dihydromyrcenol
Creative Formulasall at < 0.1%: Debaser in Bloom, Journey Woman, P.33
Rocket leaf (5.4%), Tulip sylvestre (2.73%), Mango a cv. Langra (2.41%), Jasmine rose absolute (0.88%), Cornmint (0.49%), Mentha longifolia (0.15%), Artemisia campestris (0.1%), Mastic gum (0.1%), Mentha x villosa (0.1%), Pelargonium sidoides (0.1%), Peppermint (0.08%), Artemisia variabilis (0.05%), Mentha asiatica (0.03%), Genet absolute (0.02%)
Average content per species across published analyses, indexed by Essential Oil University.
Also known by 37 other names
(3Z)-; (Z)-; (Z)-3-; (Z)-iso; [(Z)-; butanoic acid, 3-methyl-, (3Z)-3-hexen-1-yl ester; butanoic acid, 3-methyl-, (3Z)-3-hexenyl ester; butanoic acid, 3-methyl-, 3-hexenyl ester, (Z)-; butyric acid, 3-methyl-, (Z)-hex-3-en-1-yl ester; C3; cis 3-; hex-3-en-1-yl 3-methylbutanoate; hex-3-enyl 3-methyl butanoate; hex-3-enyl isovalerate; hex-3-enyl] 3-methylbutanoate; hexen-1-yl 3-methyl butanoate; hexen-1-yl isopentanoate; hexen-1-yl isovalerate; hexenyl 3-methylbutanoate; hexenyl 3-methylbutyrate; hexenyl cis-3 isovalerate; hexenyl cis-3 isovalerate (3-methylbutyrate); hexenyl i-valerate; hexenyl iso valerate; hexenyl isopentanoate; hexenyl isovalerate natural; hexenyl isovaleratefcc, no antioxidant; hexenyl-cis-3-iso-valerate FCC; hexyl isovalerianate; iso; methyl butanoic acid (3Z)-3-hexen-1-yl ester; valeric acid 3-hexen-1-yl ester; valeric acid cis-3-hexenyl ester; valeric acid, 3-hexenyl ester, (Z)-; Butanoic acid, 3-methyl-, (Z)-3-hexenyl ester; Butanoic acid, 3-methyl, hexenyl ester (unknown structure); Hexenyl isovalerate (unknown structure)
Statistics drawn from published GCMS analyses, commercial and demonstration formulas. References to third-party perfumes, brand names and trade marks are solely for identification and comparison. Formulas not made, supplied, licensed, authorised, sponsored or endorsed by the manufacturer or trade mark owner.
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General Disclaimer
(a) Vegan labelling: Where the word “vegan” is used in relation to our products, that indicates that we have not added any animal products to products marked vegan. We do not verify whether any third-party supplier has used animal additives prior to supplying a product to us. We provide products marked vegan “as is” and make no representation as to the accuracy, completeness, or reliability of that claim.
(b) Natural labelling: Where the word “natural” is used in relation to our products, that indicates that we have not added any synthetic additives to products marked natural. We do not verify whether any third-party supplier has used synthetic additives prior to supplying a product to us. We provide products marked natural “as is” and make no representation as to the accuracy, completeness, or reliability of that claim.
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(d) Demonstration formulas: Demonstration formulas are provided as a guide only. We provide no warranties or guarantees in relation to the formula. You access and use the formula at your own risk. These are independent Fraterworks reconstructions based on our own GCMS and olfactory analysis. They are not the manufacturers' original formulas and have not been supplied, authorised, licensed, sponsored or endorsed by the manufacturers. Brand and perfume names are used solely to identify the subject of the analysis and comparison. Any implied conditions or warranties are excluded and, to the extent that they cannot be excluded, any liability we have to you or any other person or entity in respect of the formula is limited to NZD0.01 (one cent). You indemnify us against any loss we suffer or incur as a direct or indirect result of your use of a formula.
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Regulations
DisclaimerAll of our products are compliant with EU 1223/2009 and the NZCPGS. None of our bases contain prohibited materials and regulatory compliance is possible depending on usage.
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All of our bases can be used in products requiring conformity with the latest IFRA standards. Fraterworks is an official member of IFRA and the FFAANZ.
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Nitro Musks
Some of our products may contain small amounts of EU and IFRA compliant musk ketone. We never use musk xylene, musk ambrette or any other prohibited materials.
Cis-3-Hexenyl Isovalerate