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    Methyl 2-Methyl Butyrate

    Methyl 2-Methyl Butyrate

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    Grade: Fraterworks® Signature Green apple sparkle in a single molecule. The juicy brightness that brings life to blends. Ethereal apple freshness with maximum lift effect.

    Aroma Chemicals

    CAS: 868-57-5 Classification: Top Note[i]

    This remarkable ester opens with an immediately recognisable burst of fresh green apple that captures that crisp, first-bite sensation. Its ethereal quality provides tremendous volatility and lift, creating a sparkling opening that radiates from the skin. Unlike heavier fruit materials, it delivers clean brightness without weight or density.

    Your formulations benefit from its exceptional potency—detectable at just 0.92 parts per billion. This extreme sensitivity means tiny additions create massive impact, making it invaluable for boosting the perceived freshness of fruit accords. The material's unique ability to bridge fruity and floral territories stems from its subtle lily-of-the-valley undertones, allowing seamless integration into white floral compositions.

    Use it strategically as a brightness catalyst rather than a dominant note. Its fleeting nature makes it perfect for creating dynamic fragrance openings that quickly recede to reveal heart materials. Combine with Ethyl 2-Methylbutyrate for fuller apple effects, or blend with cis-3-Hexenol for authentic Granny Smith apple accords. Its natural occurrence across numerous fruits validates its role in creating realistic, mouth-watering effects.

    Methyl 2-Methyl vs Ethyl 2-Methyl

    The fundamental difference lies in the alcohol portion of these esters. Methyl 2-Methylbutyrate uses methanol as its alcohol component (C6H12O2, MW 116.16), while Ethyl 2-Methylbutyrate uses ethanol (C7H14O2, MW 130.18). This seemingly small structural change creates significant performance differences. The methyl version is more volatile with a lower boiling point (115°C vs 130°C), making it extremely fleeting and ethereal. The ethyl version lasts longer and delivers more powerful, diffusive impact. Olfactively, Methyl 2-Methylbutyrate provides a crisp green apple sparkle that flashes off quickly, perfect for creating momentary brightness. Ethyl 2-Methylbutyrate offers a broader, sweeter red apple-to-tropical fruit profile with greater staying power and radiance. Choose the methyl version when you need pure ethereal lift without commitment to a fruity theme. Select the ethyl version when you want substantial fruity body in your top notes that bridges into the heart composition.

    IFRA 51: Details coming soon…
    Average Use: 0.89% in a perfume compound

    Odour Family: Fruity
    Appearance: Colourless liquid
    Longevity:

    Odour Profile: Methyl 2-Methylbutyrate delivers a bright, ethereal green apple aroma with fresh, ripe, and pulpy fruit character, enhanced by powerful lift and juicy brightness alongside subtle powdery, fatty, and lily-of-the-valley undertones.

    Uses: Essential top-note modifier providing ethereal lift, creates realistic apple-strawberry accords, adds juicy brightness to compositions.

    INCI Name: METHYL 2-METHYLBUTANOATE
    IUPAC Name: methyl 2-methylbutanoate

    General Information

    Like most suppliers and makers of quality raw materials for fragrances, we do not filter many of our products. This ensures that no odiferous matter is lost prior to use but can result in the appearance of small particles or slight clouding.

    All alcoholic fragrances should be macerated for up to a month and then chilled in a moderate freezer overnight before being filtered fine. This will remove all cloudiness or detritus and is the industry norm.

    IFRA Standards

    Permitted amounts in finished product:

    IFRA 51: Coming Soon
    IFRA 49: Coming Soon

    These are derived from calculated concentrations which do not replace chromatographic quantification on individual lots. Disclaimer...

    For Trade Use Only

    Our products are intended as building blocks in the perfume creation process; they are not to be applied to the skin undiluted.

    These raw materials are for use by the perfumery trade only.

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    Our materials comply with IFRA and EU 1223/2009 regulations for safety and quality.

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    General Disclaimer

    (a) Vegan labelling: Where the word “vegan” is used in relation to our products, that indicates that we have not added any animal products to products marked vegan. We do not verify whether any third-party supplier has used animal additives prior to supplying a product to us. We provide products marked vegan “as is” and make no representation as to the accuracy, completeness, or reliability of that claim.

    (b) Natural labelling: Where the word “natural” is used in relation to our products, that indicates that we have not added any synthetic additives to products marked natural. We do not verify whether any third-party supplier has used synthetic additives prior to supplying a product to us. We provide products marked natural “as is” and make no representation as to the accuracy, completeness, or reliability of that claim.

    (c) Documentation: We provide the information contained in each document you obtain from us (including but not limited to SDS, IFRA certificate, COA, TDS, EU Allergens, and any other regulatory document) “as is” and make no representation as to its accuracy, completeness, or reliability. We provide no warranties or guarantees in relation to a document you obtain from us. You purchase and use a document or documents at your own risk. Any implied conditions or warranties are excluded and, to the extent that they cannot be excluded, any liability we have to you or any other person or entity in respect of a document you obtain from us is limited to NZD0.01 (one cent). You indemnify us against any loss we suffer or incur as a direct or indirect result of your use of a document you obtain from us.

    (d) Demonstration formulas: Demonstration formulas are provided as a guide only. We provide no warranties or guarantees in relation to the formula. You access and use the formula at your own risk. Any implied conditions or warranties are excluded and, to the extent that they cannot be excluded, any liability we have to you or any other person or entity in respect of the formula is limited to NZD0.01 (one cent). You indemnify us against any loss we suffer or incur as a direct or indirect result of your use of a formula.

    Note: Wherever you are a professional perfumer or a hobbyist, we have what you need — from essential oils and absolutes, to bases, perfume chemicals (synthetics), bottles and more. We also offer compounding (contract blend), fragrance formulation, and an artisan lab visit for a guided smelling experience. Please note that we are not selling perfumes and that our materials are for use by perfume creation. We ship all around the world and have customer service that is second to none. We also stock educational kits and sample kits.

    • Regulations

      All of our products are compliant with EU 1223/2009 and the NZCPGS. None of our bases contain prohibited materials and regulatory compliance is possible depending on usage.

      Disclaimer 
    • IFRA Conformity

      All of our bases can be used in products requiring conformity with the latest IFRA standards. Fraterworks is an official member of IFRA and the FFAANZ.

    • Nitro Musks

      Some of our products may contain small amounts of EU and IFRA compliant musk ketone. We never use musk xylene, musk ambrette or any other prohibited materials.