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    Petitgrain Bigarade Oil

    Petitgrain Bigarade Oil

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    Manufacturer: Classic bridge between citrus and florals. Napoleon's favourite cologne ingredient. The green soul of bitter orange trees.

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    🍊Citrus Suite | Essential Oils

    CAS: 789957-91-5
    Variety: Citrus aurantium, (L) Classification: Top Note[i]

    Petitgrain Bigarade is the extraction of the foliage from bitter orange trees (the fruit of which is used for classic Seville orange marmalade). Of all the petitgrain oils, this is probably the most widely used for fine fragrance.

    This oil is extracted exclusively from the bitter orange tree making it the finest type, different from the lower quality so-called “Bigarade (Paraguay)” variants that flood the market. Petitgrain Paraguay is extracted from hybrid trees which cross the bitter orange with sweet (or other) varieties. Pure Petitgrain Bigarade is much more rare and considerably more beautiful.

    Origin: Italy
    Part: Foliage
    Method: Steam distilled at source

    Country of Origin
    Italy
    IFRA 51
    40% in finished product (Cat. 4)
    Odour Family
    Green
    Appearance
    Dark green liquid
    Longevity
    Lasts 4 hours on a smelling strip.
    Odour Profile

    Petitgrain Bigarade Oil delivers a powerful burst of fresh, bitter-green citrus with distinctive floral neroli-like facets, followed by herbaceous, woody undertones that create a sophisticated, natural bridge between citrus and florals.

    Uses

    Essential bridge ingredient for cologne, fougère, and chypre structures; provides bitter-green lift and natural complexity.

    Fraterworks® is strictly a reseller of this product and is neither an agent nor official distributor for Capua 1880, and is not affiliated with or endorsed by them.

    General Information

    Like most suppliers and makers of quality raw materials for fragrances, we do not filter many of our products. This ensures that no odiferous matter is lost prior to use but can result in the appearance of small particles or slight clouding.

    All alcoholic fragrances should be macerated for up to a month and then chilled in a moderate freezer overnight before being filtered fine. This will remove all cloudiness or detritus and is the industry norm.

    IFRA Standards

    Permitted amounts in finished product:

    IFRA 51: 40%
    IFRA 49: 100%

    These are derived from calculated concentrations which do not replace chromatographic quantification on individual lots. Disclaimer...

    For Trade Use Only

    Our products are intended as building blocks in the perfume creation process; they are not to be applied to the skin undiluted.

    These raw materials are for use by the perfumery trade only.

    View full details
    SDS IFRA 51 EU Allergens Spec
    From our research lab

    Usage in Perfumery

    Petitgrain Bigarade Oil appears in 1% of the perfumes we have analysed, at a median of 1.1% of the concentrate.

    1.1% Median use in perfumes1.5% in bases
    1.76% Average use5.77% in bases
    tr. Minimum observed0.2% in bases
    10% Maximum observed27% in bases
    Odour
    Floral, green, orange, flower, citrus
    Family
    Green
    Substantivity
    4 hours on a smelling strip
    Often used alongside
    Found in these perfumes

    Free formulasPivet Pompeia (10%), Santa Maria Novella Caprifoglio (6.5%), Fougère Royale (6%), Terre d'Hermès (4%), Eau de Coty (4%), Patou Pour Homme (2.88%), Fougere Classique (2.5%), Après L'Ondée (2%), 1740 Marquis de Sade (2%), Aventus Vintage (1.5%), Cuir Cannage (1.2%), Helumt Lang Cologne (1%), Iris Gris (1%)

    Creative Formulas212 Men (0.1–10%), 212 VIP Rosé, Aqva Pour Homme, At The Barber's, Au Coeur du Désert, Azaran, Black Opium Over Red, Black Opium, Black Saffron, Buongiorno, Cactus Garden, Carnal Flower, Cedro di Taormina, Chance EDP, Cipresso di Toscana, Code Parfum, Cologne Indélébile, Colonia Ebano, Colonia Pura, Colonia Sandalo, D. Homme Cologne, Daisy, Eau des Merveilles, Eau S. Parfum, Eidesis, Frenchy Lavande, Gardénia Antigua, Geranium Pour Monsieur, Grey Vetiver Parfum, Imitation Woman, Infusion d'Iris, Invictus Platinum, Isola Sol, K. Flower, L’Air du Désert Marocain Noir, L'air du Désert Marocain, L'Homme Ideal EDP, Lanv. for Men Vintage, Libre, Limette 37, Mandarine Basilic, Manhattan, Nectarine Blossom & Honey, Néroli Outrenoir, Noir Extreme Parfum, Noir Pour Femme, Ombre Noire, Oud Noir Intense, P. L'Homme, Pasión for Him, Platinum Égoïste, Poison EDT, Pure Oud, Renaissance, Sandalo, Scandal Parfum Cologne, Sole di Positano, Tubereuse 40, Virēre, Acqua di G. Profumo (< 0.1%), Aqva Pour Homme Marine, Bergamote 22, Crystal Saffron, Do Son EDP, Eau de Soleil Blanc 2025, Guidance, Matière Noire, MYSLF, Reflection Man, Royal Mayfair 2024, Safanad, Safari for Men, Symphonium

    Also known by 65 other names

    bigarade; bitter; citrus aurantium absolute morocco; citrus aurantium leaf absolute france; citrus aurantium leaf concrete; citrus aurantium leaf oil; citrus aurantium leaf oil (bigarade); citrus aurantium leaf oil morocco; citrus aurantium leaf oil paraguay; citrus reticulata blanco mandarin leaf oil; citrus reticulata blanco mandarin leaf oil terpeneless; citrus reticulata blanco var. mandarin leaf oil; citrus reticulata blanco var. mandarin leaf oil terpeneless; essential oil obtained from the leaves of the sour orange, citrus aurantium, rutaceae; mandarin; mandarin leaf oil; mandarin oil petitgrain natural; mandarin oil petitgrain terpeneless natural; oil mandarin petitgrain; oil mandarin petitgrain terpeneless (natural dimethyl anthranilate 98%); oil petitgrain S.A. cordillera extra FCC; oil petitgrain S.A. perfumery; orange leaf oil (citrus aurantium); petinerol; petinerol paraguay; petitgrain absolute maroc; petitgrain bigarade concrete; petitgrain bigarade ess nat 01; petitgrain bigarade oil bio; petitgrain bigarade oil egypt; petitgrain bigarade oil tunisia; petitgrain bigarade tunis EO; petitgrain ess BM 01 (Charabot); petitgrain ess BM 04 (Charabot); petitgrain ess TBM 06 (Charabot); petitgrain ess type; petitgrain ess. oil (for fragrance) (Robertet); petitgrain essential oil; petitgrain essential oil mandarin; petitgrain mandarin essential oil; petitgrain mandarin oil; petitgrain mandarin oil egypt; petitgrain mandarinier egypte EO; petitgrain mandarinier ess. oil (for fragrance) (Robertet); petitgrain oil; petitgrain oil (citrus aurantium); petitgrain oil bigarade; petitgrain oil mandarinier; petitgrain oil moroccan FCC; petitgrain oil morocco; petitgrain oil organic; petitgrain oil paraguay; petitgrain oil paraguay FCC; petitgrain oil paraguay, organic; petitgrain oil redisitlled FCC; petitgrain oil S.A.; petitgrain oil SA FCC; petitgrain oil terpeneless; petitgrain oil, bigarade; petitgrain oil, paraguay; petitgrain oil, S.A.; petitgrain organic oil morocco; petitgrain paraguay EO; petitgrain paraguay essential oil; petitgrain paraguay oil (citrus aurantium)

    Statistics drawn from published GCMS analyses, commercial and demonstration formulas. References to third-party perfumes, brand names and trade marks are solely for identification and comparison. Formulas not made, supplied, licensed, authorised, sponsored or endorsed by the manufacturer or trade mark owner.

    From the published literature

    What Bitter orange leaf is made of

    A Fraterworks analysis of the published chemical compositions of Citrus aurantium L, showing the median and observed range of each constituent across 49 studies.

    Fraterworks Composition Combined from 49 published analyses — median and observed range
    Constituent CAS Median Range
    Linalool 78-70-6 30.3% 0.16–95.21%
    Linalyl acetate 115-95-7 16.46% 0.18–92.05%
    Limonene 138-86-3 9.34% 0.2–96.41%
    Linalool oxides (cis/trans) (unknown isomers) 2.65% 0.2–5.1%
    alpha-Terpineol 98-55-5 2.59% 0–19.8%
    Nerolidol (unknown isomer) 7212-44-4 2.15% 0.1–7.6%
    Geraniol 106-24-1 1.71% 0.01–8.25%
    beta-Ocimene 13877-91-3 1.7% 0.3–3.91%
    Myrcene 123-35-3 1.7% 0.01–7.34%
    beta-Pinene 127-91-3 1.5% 0.01–30%
    beta-Ocimene (total isomers) 3779-61-1 1.48% 0.02–12.1%
    Farnesol (unknown isomer) 4602-84-0 1% 0.01–8.7%
    Geranyl acetate 105-87-3 1% 0.01–5.5%
    beta-Bisabolene 495-61-4 0.96% 0.01–1.32%
    Nerol 106-25-2 0.77% 0.01–2.86%
    Farnesol (total isomers) 3790-71-4 0.715% 0.01–1.57%
    Elemol 639-99-6 0.7% 0.7%
    Phenylacetonitrile 140-29-4 0.7% 0.67–2.5%
    Neryl acetate 141-12-8 0.695% 0.01–2.9%
    Nerolidol (total isomers) 40716-66-3 0.69% 0.01–3.36%
    2-Phenylethanol 60-12-8 0.64% 0.01–4.5%
    Citronellol 106-22-9 0.55% 0.01–4.08%
    beta-Terpineol 138-87-4 0.51% 0.01–0.85%
    meta-Cymene 535-77-3 0.5% 0.5%
    Sabinene 3387-41-5 0.5% 0.02–9.53%
    alpha-Pinene 80-56-8 0.48% 0.01–3%
    beta-Caryophyllene 87-44-5 0.45% 0.01–2.78%
    Meranzin 23971-42-8 0.45% 0.4–0.5%
    Eugenol 97-53-0 0.4% 0.3–0.5%
    Methyl heptenone (unknown structure) 409-02-9 0.32% 0.32%
    Indole 120-72-9 0.305% 0.05–4.5%
    (E)-2-Hexenal 6728-26-3 0.3% 0.3%
    Aromadendrene 72747-25-2 0.3% 0.3%
    Methyl anthranilate 134-20-3 0.3% 0.01–5.8%
    Sesquiterpene hydrocarbons (unknown) 0.29% 0.29%
    Linalool oxide (6) (pyranoid) (total isomers) 14009-71-3 0.285% 0.02–0.77%
    Terpinen-4-ol 562-74-3 0.26% 0.01–4%
    beta-Phellandrene 555-10-2 0.25% 0.01–3.33%
    beta-Copaene 18252-44-3 0.23% 0.23%
    cis-alpha-Bisabolene 29837-07-8 0.2% 0.2%
    Geranyl formate 105-86-2 0.2% 0.2%
    Terpinolene 586-62-9 0.2% 0.01–0.9%
    gamma-Terpinene 99-85-4 0.18% 0.01–15%
    Ethyl acetate 141-78-6 0.175% 0.05–0.3%
    Isocaryophyllene 118-65-0 0.155% 0.09–0.22%
    Osthol 484-12-8 0.15% 0.1–0.2%
    p-Menth-2-en-1-ol (total isomers) 29803-81-4 0.15% 0.02–0.28%
    Benzyl alcohol 100-51-6 0.15% 0.15%
    Carveol (total isomers) 1197-07-5 0.135% 0.01–0.98%
    Linalool oxide (5) (furanoid) (total isomers) 34995-77-2 0.13% 0.01–12.53%
    Decanal 112-31-2 0.12% 0.01–0.2%
    Benzaldehyde 100-52-7 0.115% 0.01–0.22%
    2-Phenylethyl acetate 103-45-7 0.105% 0.03–0.18%
    (2Z,6E)-Farnesal 4380-32-9 0.1% 0.1%
    Acetaldehyde 75-07-0 0.1% 0.1%
    alpha-Terpinene 99-86-5 0.1% 0.01–5.64%
    alpha-Terpinyl acetate 80-26-2 0.1% 0.01–1.2%
    cis-/trans-Anhydrolinalooloxides 13679-86-2 0.1% 0.1%
    Cumin alcohol 536-60-7 0.1% 0.1%
    Cyclofenchene 488-97-1 0.1% 0.1%
    Ethanol 64-17-5 0.1% 0.1%
    Germacrene D 23986-74-5 0.1% 0.04–0.2%
    Methanol 67-56-1 0.1% 0.1%
    Methyl N-methyl anthranilate 85-91-6 0.1% 0.05–3.18%
    Toluene 108-88-3 0.1% 0.1%
    para-Cymene 99-87-6 0.095% 0.01–5%
    Bicyclogermacrene 24703-35-3 0.09% 0.01–0.17%
    Limonene dioxide 0.09% 0.09%
    Octanal 124-13-0 0.09% 0.01–0.6%
    Limonene oxide (unknown structure) 4959-35-7 0.085% 0.02–0.15%
    6-Methyl-5-hepten-2-one 110-93-0 0.08% 0.05–0.11%
    beta-Farnesene (total isomers) 18794-84-8 0.08% 0.01–0.54%
    Nootkatone 4674-50-4 0.08% 0.01–0.13%
    Spathulenol 6750-60-3 0.08% 0.02–0.5%
    alpha-Farnesene (total isomers) 502-61-4 0.075% 0.03–0.11%
    Geranial 141-27-5 0.07% 0.01–1.5%
    p-Mentha-1,4-dien-7-ol 22539-72-6 0.07% 0.07%
    1-Octanol 111-87-5 0.065% 0.01–0.34%
    Decyl acetate 112-17-4 0.065% 0.03–0.1%
    delta-3-Carene 13466-78-9 0.065% 0.01–1%
    gamma-Elemene 30824-67-0 0.065% 0.01–0.12%
    Bisabolene (unknown isomer) 0.06% 0.02–0.1%
    (E,Z)-Farnesyl acetate 24163-98-2 0.06% 0.03–0.09%
    alpha-Humulene 6753-98-6 0.06% 0.01–1.35%
    beta-Elemene 515-13-9 0.055% 0.01–1.63%
    1-Propanol 71-23-8 0.05% 0.05%
    Acetone 67-64-1 0.05% 0.05%
    alpha-Phellandrene 99-83-2 0.05% 0.01–1.9%
    Carvotanacetone 499-71-8 0.05% 0.05%
    cis-Jasmone 488-10-8 0.05% 0.03–0.15%
    Citronellyl acetate 150-84-5 0.05% 0.01–0.4%
    Geranylacetone 3796-70-1 0.05% 0.05%
    Germacrene B 15423-57-1 0.05% 0.01–0.5%
    (E)-2-Hexenol 928-95-0 0.05% 0.01–0.09%
    Carvone 99-49-0 0.045% 0.01–0.14%
    Caryophyllene oxide 1139-30-6 0.045% 0.04–0.3%
    alpha,p-Dimethylstyrene 1195-32-0 0.04% 0.01–0.5%
    Hexyl acetate 142-92-7 0.04% 0.03–0.05%
    p-2,4(8)-Menthadiene 586-63-0 0.04% 0.04%
    Octyl acetate 112-14-1 0.035% 0.01–0.1%
    Citrus aurantium L., ssp. amara Engl., fam. Rutaceae
    Bitter orange leaf 1 (Petitgrain)B.M. Lawrence, Chemical Composition of Petitgrain Oil, Perf. Flav., Vol. 5, October/November 1980, no. 6, p. 28; Perf. Flav., Vol. 18, September/October 1993, no. 5, p. 46

    26 constituents reported

    Neroli bigarade (bitter orange flower) Spain 2Boelens, M.H. and Jimenez Sindreu, R., Essential Oils from Seville Bitter Orange (Citrus Aurantium L. ssp. amara) (bitter orange flower oil), B.M. Lawrence, B.D. Mookherjee and B.J. Willis (Eds.) Flavors and Fragrances: A World Perspective. Proc. 10th Int. Congress Ess. Oils, Fragr. and Flav., Washington, D.C. U.S.A. 1986, p. 551-565; Elsevier, Amsterdam (1988)

    41 constituents reported

    Orange, bitter (Spain) 1Boelens, Mans H. and Jimenez Sindreu, Rafael, Essential Oils from Seville Bitter Orange (Citrus aurantium L., ssp.amara), Flavors and Fragrances, A World Perspective, Proceedings of the International Congress of Essential Oils, Elsevier, Amsterdam 1988, 551-565 (Eds. B.M. Lawrence, B.D. Mookherjee and B.J. Willis), Elsevier, Amsterdam, 1988

    49 constituents reported

    Orange, bitter (Spain) 2Boelens, M.H., and Jimenez, R., The Chemical Composition of the Peel Oils from Unripe and Ripe Fruits of Bitter Orange, Citrus aurantium L. ssp. amara Engl., Flavour Fragr. J., Vol. 4, 139-142, (1989)

    50 constituents reported

    Bitter orange leaf (Petitgrain) (Spain) 1Boelens, M.H. and Jimenez Sindreu R., Essentials Oils from Seville Bitter Orange (Citrus aurantium L. ssp. Amara), B.M. Lawrence, B.D. Mookherjee and B.J. Willis (Eds), Flavors and Fragrances: A World Perspective. Proceedings of the 10th Int. Congress of Ess. Oils, Fragr. and Flavors, Washington DC, p. 551-565 (1986), Elsevier, Amsterdam (1988)

    36 constituents reported

    Orange, bitter (Cuba)Soulari, M., anf Fanghaenel, E., Analisis Parcial de Aceite Esencial de Naranja Agria (Citrus aurantium L.) Producido en Cuba, Rivista Cinic., Vol. 3 (1), 125-128 (1971)

    8 constituents reported

    Orange, bitter (Brazil)Koketsu, M., Maigaihaes, M.T., Wilberg, V.C., and Donaliso, M.G.R., Oleos Essenciais de Frutos Citricos Cultivados no Brazil (0.01% = trace), Bol. Pesqui EMBRAPA Cent. Technol. Agric. Aliment. (7), 21, (1983)

    30 constituents reported

    Orange, bitter (China)Lin, Z.K., Hua, Y.F., and Gu, Y.H., The Chemical Constituents of the Essential Oil from the Flowers, Leaves and Peels of Citrus aurantium (0.01% = trace), Zhiwa Xuebao, Vol. 28, 635-640 (1986)

    20 constituents reported

    Orange, bitter 2Haubruge, E., et al., Etude de la Toxicite de cinq Huiles Essentielles Extraites de Citrus etc., Med. Fac. Landbouww. Rijksuniv. Gent, Vol. 54 (3b), 1083-1093 (1989)

    17 constituents reported

    Orange, bitter 1Inoma, S., Miyagi, Y., and Akieda, T., Characterization of Citrus Oil (Mainly Orange Oil, Mandarin Oil and Tangerine Oil) (0.01% = trace), Kanzei Chuo Bunsekishoho, Vol. 29, 87-97 (1989)

    27 constituents reported

    Bitter orange leaf 3 (Petitgrain)Haubrage,E., Lognay,G., Marlier,M., Danhier,P. Gilson,J.C. & Gaspar,Ch., Etude de la toxicite de cinq huiles essentielles extraites de Citrus sp., Med. Fac. Landbouww. Rijksuniv. Gent, Vol. 54, 1083-1093 (1989)

    24 constituents reported

    Bitter orange leaf 2 (Petitgrain)Formacek, K., and Kubeczka, K.H., Essential Oils Analysis by Capillary Crhomatography and Carbon-13 NMR Spectroscopy, pp. 213, 214, book: see Title, John Wiley & Sons, New York (1982)

    20 constituents reported

    Orange, bitter (Italy)G. Dugo, A. Verzera, I.S. d'Alcontres, A. Crotoneo & R. Ficarra, On the genuineness of Citrus essential oils. Part LXI. Italian bitter orange essential oil: Composition and detection of contamination etc., Flavour Fragr. J., Vol. 8, 25-33 (1993)

    60 constituents reported

    Neroli bigarade (bitter orange flower) China 3Liangfeng Zhu, Li Yonghua, Li Baoling, Lu Biyao & Xia Nianhe, Aromatic Plants and Essential Constituents, p. 64 (bitter orange flower oil), South China Institute of Botany, Chinese Academy of Sciences, Hai Feng Publishing Co., Chinese National Node for APINMAP, distributed by Peace Book Co. Ltd., Hong Kong (1993)

    25 constituents reported

    Bitter orange leaf (Petitgrain) (Japan)Kamiyama, S., & M. Amaha, Studies on leaf oils of Citrus species. VI. Composition of leaf oils from ten Citrus Taxa and some intrageneric hybrids (0.01% = trace), Bull. Brew. Sci., Vol. 18, 17-27 (1972)

    36 constituents reported

    Bitter orange leaf (Petitgrain) (USA) 1Ortiz, J.M., J. Kumamoto & R.W. Scora, Possible relationships among sour oranges by analysis of their essentials (average percentage in oils of a series of varieties), Int. Flav. Food Addit., 224-226 (1978)

    22 constituents reported

    Bitter orange leaf (Petitgrain) (China) 1Lin, Z.-K., Y.-F. Hua & Y.-H. Gu, The chemical constituents of the essential oil from the flowers, leaves and peels of Citrus aurantium, Ziwu Xuebao (Acta Botanica Sinica, Vol. 28, 635-640 (1986)

    32 constituents reported

    Bitter orange leaf (Petitgrain) (Spain) 2Boelens, M.H. and Oporto, A., Natural Isolates from Seville Bitter Orange Tree, Perf. Flav., Vol. 16, November/December 1991, 1-7

    51 constituents reported

    Bitter orange leaf (Petitgrain) (Mauritius)Gurib-Fakim, A., and Demarne, F., Aromatic Plants of Mauritius: Volatile Constituents of the Leaf Oils of Citrus aurantium L., Citrus paradisi Macfad and C. sinensis (L.) Osbekc, J. Essent. Oil Res., Vol. 7, 105-109 (Jan/Feb 1995)

    17 constituents reported

    Bitter orange leaf (Petitgrain) (Italy) 1Dugo, G., et al., Characterization of Italian Citrus Petitgrain Oils (average analysis of 5 industrial oil samples), Perf. Flav., Vol. 21, 17-28 (May/June 1996)

    60 constituents reported

    • Linalyl acetate115-95-755.5%
    • Linalool78-70-626.5%
    • alpha-Terpineol98-55-54.36%
    • Geranyl acetate105-87-32.53%
    • Neryl acetate141-12-81.38%
    • Limonene138-86-31.3%
    • (E)-beta-Ocimene 3779-61-11.16%
    • beta-Pinene127-91-30.9%
    • Myrcene123-35-30.9%
    • Nerol106-25-20.87%
    • Geraniol106-24-10.83%
    • beta-Caryophyllene87-44-50.55%
    • Geranial 141-27-50.51%
    • delta-3-Carene 13466-78-90.33%
    • (Z)-beta-Ocimene 3338-55-40.32%
    • Neral 106-26-30.32%
    • Sabinene3387-41-50.18%
    • Bicyclogermacrene 24703-35-30.17%
    • alpha-Pinene80-56-80.16%
    • Terpinolene586-62-90.15%
    • alpha-Terpinyl acetate80-26-20.12%
    • Spathulenol 6750-60-30.08%
    • Terpinen-4-ol562-74-30.07%
    • Methyl N-methyl anthranilate 85-91-60.07%
    • (E)-Nerolidol 40716-66-30.06%
    • cis-Linalool oxide (5) (furanoid) 5989-33-30.06%
    • 6-Methyl-5-hepten-2-one 110-93-00.05%
    • (Z)-beta-Farnesene 28973-97-90.05%
    • Caryophyllene oxide1139-30-60.05%
    • gamma-Terpinene99-85-40.05%
    • para-Cymene 99-87-60.05%
    • alpha-Humulene 6753-98-60.05%
    • alpha,p-Dimethylstyrene 1195-32-00.04%
    • p-2,4(8)-Menthadiene 586-63-00.04%
    • beta-Phellandrene 555-10-20.03%
    • Nonanal124-19-60.03%
    • 1,8-Cineole470-82-60.03%
    • Linalyl propionate144-39-80.03%
    • (E,E)-alpha-Farnesene502-61-40.03%
    • Citronellal106-23-00.02%
    • trans-Linalool oxide (5) (furanoid) 34995-77-20.02%
    • Methyl geranate 2349-14-60.02%
    • delta-Cadinene 483-76-10.02%
    • alpha-Phellandrene 99-83-20.02%
    • trans-p-Menth-2-en-1-ol 29803-81-40.01%
    • cis-p-Menth-2-en-1-ol 29803-82-50.01%
    • alpha-Fenchene 471-84-10.01%
    • trans-beta-Bergamotene 15438-94-50.01%
    • delta-Elemene 20307-84-00.01%
    • beta-Elemene 515-13-90.01%
    • alpha-Cubebene 17699-14-80.01%
    • cis-Sabinene hydrate 15537-55-00.01%
    • ortho-Cymene 527-84-40.01%
    • alpha-Copaene 3856-25-50.01%
    • beta-Bisabolene 495-61-40.01%
    • Citronellyl acetate150-84-50.01%
    • alpha-Terpinene 99-86-50.01%
    • Camphene 79-92-50.01%
    • alpha-Thujene 3917-48-40.01%
    • Tricyclene 508-32-70.01%
    Neroli bigarade (bitter orange flower) Italy 3Mondello, L., Dugo, G., Dugo, P., and Bartle, K.D., On-Line HPLC-HRGC in the Analytical Chemistry of Citrus Essential Oils, Perf. Flav., Vol. 21, July/August 1996, 25-49

    56 constituents reported

    • Limonene138-86-324.57%
    • beta-Pinene127-91-318.22%
    • Linalool78-70-615.59%
    • Linalyl acetate115-95-79.76%
    • gamma-Terpinene99-85-43.71%
    • (E)-beta-Ocimene 3779-61-13.6%
    • Methyl N-methyl anthranilate 85-91-63.18%
    • Myrcene123-35-32.33%
    • Sabinene3387-41-52%
    • alpha-Terpineol98-55-51.79%
    • (E)-Nerolidol 40716-66-31.76%
    • beta-Elemene 515-13-91.63%
    • alpha-Pinene80-56-81.31%
    • Terpinen-4-ol562-74-31.2%
    • para-Cymene 99-87-61.04%
    • (Z,E)-Farnesol 3790-71-40.98%
    • Neryl acetate141-12-80.92%
    • beta-Caryophyllene87-44-50.72%
    • Nerol106-25-20.69%
    • Geranial 141-27-50.65%
    • Terpinolene586-62-90.53%
    • delta-3-Carene 13466-78-90.52%
    • alpha-Terpinene 99-86-50.51%
    • Neral 106-26-30.41%
    • (Z)-beta-Ocimene 3338-55-40.34%
    • Sesquiterpene hydrocarbons (unknown) 0.29%
    • trans-p-Menth-2-en-1-ol 29803-81-40.19%
    • (Z)-beta-Farnesene 28973-97-90.14%
    • 6-Methyl-5-hepten-2-one 110-93-00.11%
    • Methyl anthranilate134-20-30.11%
    • alpha-Humulene 6753-98-60.1%
    • alpha-Phellandrene 99-83-20.09%
    • trans-Sabinene hydrate 17699-16-00.09%
    • cis-p-Menth-2-en-1-ol 29803-82-50.09%
    • alpha-Farnesene0.07%
    • Citronellal106-23-00.06%
    • Indole120-72-90.06%
    • alpha-Thujene 3917-48-40.05%
    • alpha-Terpinyl acetate80-26-20.05%
    • Germacrene D 23986-74-50.05%
    • Camphene 79-92-50.04%
    • Caryophyllene oxide1139-30-60.04%
    • Citronellyl acetate150-84-50.03%
    • cis-Sabinene hydrate 15537-55-00.03%
    • trans-Piperitol 16721-39-40.03%
    • delta-Cadinene 483-76-10.03%
    • Spathulenol 6750-60-30.02%
    • alpha-Cadinol 481-34-50.02%
    • trans-alpha-Bergamotene 13474-59-40.02%
    • cis-Linalool oxide (unknown isomer) 0.02%
    • Tricyclene 508-32-70.01%
    • Benzaldehyde 100-52-70.01%
    • 2-Phenylethanol60-12-80.01%
    • Globulol 0.01%
    • (E,E)-Farnesol 106-28-50.01%
    • (Z)-Nerolidol 3790-78-10.01%
    Neroli bigarade (bitter orange flower) Spain 3Boelens, M.H., and Boelens, H.H., Differences in Chemical and Sensory Properties of Orange Flower and Rose Oils obtained from Hydrodistillation and from Supercritical CO2 Extraction, Perf. Flav., Vol. 22, May/June 1997, 31-35

    41 constituents reported

    Neroli bigarade (bitter orange flower) Tunisia 2Boelens, M.H., and Boelens, H.H., Differences in Chemical and Sensory Properties of Orange Flower and Rose Oils Obtained from Hydrodistillation and from Supercirtical CO2 Extraction, Perf. Flav. Vol. 22, May/June 1997, 31-35

    41 constituents reported

    Neroli bigarade (bitter orange flower) MoroccoBoelens, M.H., and Boelens, H.H., Differences in Chemical and Sensory Properties of Orange Flower and Rose Oil Obtained from Hydrodistillation and from Supercritical CO2 Extraction, Perf. Flav., Vol. 22, May/June 1997, 31-35

    36 constituents reported

    Neroli bigarade (bitter orange flower) 1Buccellato, F., Orange blossom, Perf. Flavor., Vol. 6 (3), 31-34 (1981)

    18 constituents reported

    Bitter orange flower absolute 1Buccellato, F., Orange blossom, Perfum. Flavor., Vol. 6(3), 31-34 (1981)

    21 constituents reported

    Bitter orange flower water absolute 1Buccellato, F., Orange blossom, Perfum. Flavor., Vol. 6 (3), 31-34 (1981)

    17 constituents reported

    Neroli bigarade (bitter orange flower) Spain 1Srinivas, S.R., Atlas of essential oils, see Title: published by author, Bronx, NY (1986)

    24 constituents reported

    Neroli bigarade (bitter orange flower) AlgeriaSrinivas, S.R., Atlas of essential oils, see Title: published by author, Bronx, NY (1986)

    21 constituents reported

    Neroli bigarade (bitter orange flower) Italy 1Srinivas, S.R., Atlas of essential oils, see Title: published by author, Bronx, NY (1986)

    23 constituents reported

    Neroli bigarade (bitter orange flower) Tunesia 1Srinivas, S.R., Atlas of essential oils, see Title: published by author, Bronx, NY (1986)

    23 constituents reported

    Neroli bigarade (bitter orange flower) EgyptSrinivas, S.R., Atlas of essential oils, see Title: published by author, Bronx, NY (1986)

    24 constituents reported

    Neroli bigarade (bitter orange flower) 2Prager, M.J., and Miskiewicz, M.A., Gas chromatographic/mass spectrometric analysis identification and detection of adulteration of perfumery products from bitter orange trees, J. Assoc. Offic.. Anal. Chem., Vol. 64, 131-138 (1981)

    20 constituents reported

    Bitter orange flower water absolute 2Prager, M.J., and Miskiewicz, M.A., Gas chromatographic/mass spectrometric analysis identification and detection of adulteration of perfumery products from bitter orange trees, J. Assoc. Offic. Anal. Chem., Vol. 64, 131-136 (1981)

    19 constituents reported

    Bitter orange flower absolute 2Prager, M.J., and Miskiewicz, M.A., Gas chromatographic/mass spectrometric analysis identification and detection of adulteration of perfumery products from bitter orange trees, J. Assoc. Offic. Anal. Chem., Vol. 64, 131-138 (1981)

    19 constituents reported

    Neroli bigarade (bitter orange flower) China 1Lin, Z.-K., Hua, Y.-F., and Gu, Y.-H., The chemical constituents of the essential oil from the flowers, leaves and peels of Citrus aurantium, Zhiwu Xuebao, Vol. 28, 635-640 (1986)

    30 constituents reported

    Neroli bigarade (bitter orange flower) China 2Ma, L., et al., Aroma volatile constituents of Citrus aurantium var. amara Engl., Beijing Daxue Zuebao Ziran Kexueban (Acta Sci. Natural Univ. Pekinesis) Vol. 24, 687-694 (1988)

    18 constituents reported

    Bitter orange flower headspace (China)Ma, L., et al., Aroma volatile constituents of Citrus aurantium var. amara Engl., Beijing Daxue Zuebao Ziran Kexueban (Acta Sci. Natural Univ. Pekinesis) Vol. 24, 687-694 (1988)

    14 constituents reported

    • Limonene138-86-345.9%
    • beta-Pinene127-91-320.95%
    • Linalyl acetate115-95-716.69%
    • Linalool78-70-66.87%
    • beta-Phellandrene 555-10-23.33%
    • (E)-beta-Ocimene 3779-61-12.02%
    • alpha-Thujene 3917-48-41.59%
    • Myrcene123-35-30.96%
    • Isocaryophyllene 118-65-00.22%
    • alpha-Humulene 6753-98-60.11%
    • Toluene108-88-30.1%
    • Camphene 79-92-50.08%
    • trans-Linalool oxide (5) (furanoid) 34995-77-20.04%
    • cis-Linalool oxide (5) (furanoid) 5989-33-30.04%
    Neroli bigarade (bitter orange flower) Italy 2aGermana, M.A., et al., Essential oils of the flowers, leaves and buds of five species of Citrus (analysis of real flower oils), Essenze Deriv. Agrum., Vol. 60, 297-312 (1990)

    16 constituents reported

    Neroli bigarade (bitter orange flower) Italy 2bGermana, M.A., et al., Essential oils of the flowers, leaves and buds of five species of Citrus (analysis of oil from flowerbuds), Essenze Deriv. Agrum., Vol. 60, 297-312 (1990)

    16 constituents reported

    Bitter orange leaf (Petitgrain) (USA) 2Lota, M-L-. et al.,, Chemical variability of peel and leaf essential oils of sour orange (0.01% = trace), Flav. Fragr. J., 2001, Vol. 16, 89-96

    26 constituents reported

    Bitter orange leaf (Petitgrain) (Spain) 3Lota, M-L., et al.,, Chemical variability of peel and leaf essential oils of sour orange (0.01% = trace), Flav. Fragr. J., 2001, Vol. 16, 89-96

    26 constituents reported

    Bitter orange leaf (Petitgrain) (Italy) 2aAdami, M., et al.,, Estrazione di petitgrain con CO2 supercirtical (analysis of steamdistilled oil), Essenz. Deriv. Agrum., Vol. 73, 193-200 (2000)

    13 constituents reported

    Bitter orange leaf (Petitgrain) (Italy) 2bAdami, M., et al.,, Estrazione di petitgrain con CO2 supercritical (analysis of SFE extract), Essenz. Deriv. Agrum., Vol. 70, 193-200 (2000)

    13 constituents reported

    Bitter orange leaf (Petitgrain) (Italy) 2cAdami, M., et al.,, Estrazione di petitgrain con CO2 supercritical (analysis of ether extract), Essenz. Deriv. Agrum., Vol. 70, 193-200 (2000)

    13 constituents reported

    Citrus aurantium L., var. amara Engl., fam. Rutaceae
    Bitter orange flower water absolute 3Remy, M., Bayle, J.-C., Derbesy, M., and Uzio, R., The Tunisian orange flower water absolute LMR, Rivista Ital. EPPOS, (Numero speciale), 593-602 (1993)

    14 constituents reported

    Citrus aurantium L., cultivar cyathifera Y. Tanaka, fam. Rutaceae
    Daidai (Japan)Song, H.S., Sawamura, M., Ito, T., Ido, A., and Ukeda, H.,, Quantitative determination and characteristic flavour of daidai (Citrus aurantium L. var. cyathifera Y. Tanaka) peel oil (0.01% = trace), Flavour Fragr. J., 2000, Vol. 15, 323-328

    52 constituents reported

    Citrus aurantium L., ssp. amara Engler, fam. Rutaceae
    Orange, bitter 3Lota, M-L., et al.,, Chemical variabitlity of peel and leaf essential oils of sour orange (0.01% = trace), Flavour Fragr. J. 2001, Vol. 16, 89-96

    26 constituents reported

    Citrus aurantium L., ssp. amara Engl., fam Rutaceae
    Bitter orange leaf (Petitgrain) (China) 2Huang, Y-Z., Pu, Z-L., and Chen, Q-Y.,, The chemical composition of the leaf essential oils from 100 Citrus species, cultivars, hybrids and varieties of Chinese origin (3 cultivars), Perfum. Flav., Vol. 25 (1), 53-66 (2000)

    49 constituents reported

    Sources: Published studies indexed by Essential Oil University (EOUdb). Constituent harmonisation and calculations by Fraterworks.

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